The teaching of Chinese architecture history has building structures too complex, is limited to 2D planar teaching and is not easy for students to master and apply, therefore an implementation method of Chinese architecture history teaching system based on mixed reality technology was proposed. The wooden structure system of Baoguo Temple in Ningbo was taken as an example, and the mixed reality device Microsoft HoloLens was used as the teaching platform. Firstly, 3ds Max was applied to the 3D simulation modeling of the wooden structure system of Baoguo Temple based on the collected data, and a building model library was built. Then, the 3D human-computer interface of the virtual teaching system was constructed in unity3D, the key technologies were used including environment understanding and human-computer interaction based on C# scripts, and a Chinese architectural history teaching system using HoloLens was implemented with core functions of building structure recognition and cultural cognition. The results show that the system has good 3D visual effects and natural effective human-computer interaction, which can improve the efficiency of knowledge transfer and the initiative of students.